Product ID:SP2821, POTASSIUM PERMANGANATE SOLUTIONS 0.
MSDS Date:06/28/1991
FSC:6810
NIIN:00N027727
MSDS Number: BNVHH

FISHER SCIENTIFIC, CHEMICAL DIV.

1 REAGENT LANE
FAIR LAWN, NJ 07410
US

Emergency Phone: 201-796-7100/800-424-9300(CHEMTREC)

Info Phone: 201-796-7100 OR 201-796-7523

Cage: 1B464

FISHER SCIENTIFIC CO. CHEMICAL MFG DIV

FAIRLAWN, NJ 07410-2802 US

Telephone: 201-796-7100

Cage: 1B464

ALSO BE APPARENT. ADDL EFTS MAY INCL NAUS/

RTECS: 9999999ZZ

PAIN/TYMPANIC DISTENTION OF ABDOM. SHOCK RSLTG IN

RTECS: 9999999ZZ

OR ANURIA MAY APPEAR. CHRONIC-MAY RSLT IN

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POISONING MAY AFFECT THE

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MIN). IN CASE OF CHEM BURNS, COVER AREA

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WASH IMMED W/LG

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NO EVIDENCE OF CHEM REMAINS (AT LST 15-20 MIN). IN

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MEDICATION. GET MED ATTN IMMED. SOLN OF ASCORBIC

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AT REDUCING RESIDUAL PERMANGANATE &

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ACID REDUCES PERMANGANATE, & EDETATE SOLN HELPS

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FOR MORE SPECIFIC INF0 REGARDING FIRST AID

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TREAT SYMPTOMATICALLY AND SUPPORTIVELY.

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AND PLACE INTO CONTRS FOR LATER DISPOSAL. FOR

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DISPOSAL. KEEP UNNECESSARY PEOPLE AWAY. ISOLATE

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PERMANGANIC ACID, POTASSIUM SALT; (POTASSIUM PERMANGANATE)

CAS: 7722-64-7

RTECS: SD6475000

Fraction By Weight: 0.3-3%

OSHA PEL 5 MG MN/M3 CEILING

ACGIH TLV: 5 MG MN/M3

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

0.7.

CAS: 7732-18-5

RTECS: ZC0110000

Fraction By Weight: 97-99.7%

COMBUST MATTER. CONTACT W/EASILY OXIDIZABLE,

RTECS: 9999999ZZ

VIOLENT COMBUSTION OR EXPLOSION.

RTECS: 9999999ZZ

CHANGES IN MOUTH/BRONCHIAL & GI DISTURB ARE

RTECS: 9999999ZZ

SEV BURNS W/REDNESS & PAIN. CHRONIC-RPTD/PRLNG CONT

RTECS: 9999999ZZ

SOLID MAY CAUSE BURNS WITH REDNESS/PAIN/

RTECS: 9999999ZZ

ERODED LESION ACCOMPANIED BY SWELLING &

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& BROWN DISCOLORATION OF CORNEA IS POSS W/PRLNG

RTECS: 9999999ZZ

PHARYNX & LARYNX. DISCOLORATION FROM PURPLE- BROWN

RTECS: 9999999ZZ

LD50 LC50 Mixture:LD50: (ORAL, RAT) 1090 MG/KG - ING 1.
Routes of Entry: Inhalation:YES Skin:NO Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHAL: ACUTE-MAY CAUSE SEV IRRIT OF
RESP TRACT/ LABORED BRTHG/CHOKING/STRIDOR/PERSISTENT, SPASMODIC
COUGH/PAIN IN NOSE, MOUTH & THROAT/BURNS OF MUC MEMB. IF SUFFICIENT
QTYS ARE INHALED, PULM EDEMA MAY DEVELOP W/A LATENT PERIOD OF 5-72
HRS.SYMP MAY INCL TIGHTNESS IN CHEST/FROTHY SPUTUM/CYANOSIS/DIZZ.
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: PHYSICAL FINDINGS MAY INCL WEAK/RAPID
PULSE/HYPOTENSION/MOIST RALES/HEMOCONCENTRATION. RECOVERY MAY BE
PRLNG & RELAPSES ARE POSS. IN SEV EXPOS, DEATH DUE TO ANOXIA MAY
OCCUR W/IN FEW HRS AFT ER ONSET OF PULM EDEMA OR FOLLOWING A
RELAPSE. CHRONIC-MAY CAUSE EROSION OF TEETH &
INFLAMMATORY/ULCERATIVE (ING 5)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:INHAL:MOVE TO FRESH AIR IMMED. IF BRTHG STOPPED, GIVE ARTF
RESP. MAINTAIN AIRWAY/BLOOD PRESS & ADMIN O*2 IF AVAIL. KEEP
WARM/AT REST. TREAT SYMPTOMATICALLY/SUPPORTIVELY. ADMIN OF O*2 SHLD
BE PERFORMED BY QUALIFIED PERS. GET MED ATTN IMMED.SKIN:REMOVE
CONTAMD CLTHG/SHOES IMMED. WASH AFFECTED AREA W/SOAP OR MILD
DETERGENT & LG AMTS OF WATER UNTIL NO EVIDENCE OF CHEM REMAINS (AT
LST 15-20 (ING 15)

Flash Point:NOT COMBUSTIBLE
Extinguishing Media:WATER ONLY, NO DRY CHEMICAL, CARBON DIOXIDE OR
HALON. FOR LARGER FIRES, FLOOD AREA WITH WATER FROM A DISTANCE.
Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP
. MOVE CONTR FROM FIRE AREA IF W/O RISK. APPLY COOLING WATER TO
SIDE OF CONTRS EXPOSED TO FLAMES (SUPP DATA)
Unusual Fire/Explosion Hazard:NEGLIG FIRE HAZ WHEN EXPOS TO HEAT/FLAME.
OXIDIZER: OXIDIZERS DECOMP, ESPECIALLY WHEN HEATED, TO YIELD
O*2/OTHER GASES WHICH WILL INCR BURNING RATE OF (ING 3)

Spill Release Procedures:KEEP COMBUST (WOOD/PAPER/OIL/ETC) AWAY FROM
SPILLED MATL. DO NOT TOUCH SPILLED MATL. SML DRY SPILLS: W/CLEAN
SHOVEL, PLACE MATL INTO CLEAN/DRY CONTR & COVER; MOVE CONTRS FROM
SPILL AREA. SML LIQ SPILL S: TAKE UP W/SAND/EARTH/OTHER ABSORB MATL
(ING 23)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:NONE SPECIFIED BY MANUFACTURER.
Other Precautions:NONE SPECIFIED BY MANUFACTURER.

Respiratory Protection:SPECIFIC RESPIRATOR SELECTED MUST BE BASED ON
CONTAM LEVELS FOUND IN WORK PLACE/MUST BE BASED ON SPECIFIC
OPERATION/MUST NOT EXCEED WORKING LIMITS OF RESPIRATOR/MUST BE
JOINTLY APPRVD BY NIOSH/MSHA. F OR MORE SPECIFIC INFO, CONT NEHC .
Ventilation:PROVIDE LOCAL EXHAUST VENTILATION &/OR GENERAL DILUTION
VENTILATION TO MEET PUBLISHED EXPOSURE LIMITS.
Protective Gloves:IMPERVIOUS GLOVES .
Eye Protection:CHEM WORK GOGG/FULL LENGTH FSHLD .
Other Protective Equipment:APPROP PROT (IMPERVIOUS) CLTHG/EQUIP TO PVNT
SKIN CONT. EYE WASH FOUNTAIN/QUICK DRENCH SHOWER W/IN IMMED WORK
AREA.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRE FIGHT PROC: UNTIL WELL AFTER FIRE IS OUT. FOR MASSIVE FIRE, USE
UNMANNED HOSE HOLDER OR MONITOR NOZZLES; IF IMPOSS, WITHDRAW FROM
AREA & LET FIRE BURN. USE FLOODING AMTS OF WATER. COOL CONTRS W/F
LOODING QTYS OF WATER. APPLY FROM AS FAR A DISTANCE AS POSS.
EVACUATE TO A RADIUS OF 2500 FEET FOR UNCONTROLLABLE FIRES.

HCC:D1
Boiling Pt:B.P. Text:212F,100C
Melt/Freeze Pt:M.P/F.P Text:32F,0.0C
Vapor Pres:SEE ING 2
Vapor Density:SEE ING 2
Spec Gravity:1
Evaporation Rate & Reference:>1 (ETHER=1)
Appearance and Odor:PURPLE LIQUID.

Stability Indicator/Materials to Avoid:YES
NON-METALS, ORGANIC MATERIALS. FOR A COMPLETE LISTING OF MATERIALS TO
AVOID, CONTACT NEHC .
Stability Condition to Avoid:AVOID CONT W/COMBUST MATLS
(WOOD/PAPER/FUEL/OILS/ ETC); IGNITION OR EXPLOSION MAY RESULT.
AVOID CONTAM OF WATER SOURCES.
Hazardous Decomposition Products:THERMAL DECOMPOSITION PRODUCTS MAY
INCLUDE TOXIC AND HAZARDOUS OXIDES OF POTASSIUM AND MANGANESE.

Waste Disposal Methods:DISPOSAL MUST BE IN ACCORDANCE WITH FEDERAL,
STATE, AND LOCAL REGULATIONS .

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.